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          劉小明團隊

          來源 :       作者 :       時間 : 2021-06-21     點擊數:1081    打印

               


           

          團隊名稱 綠色功能材料與應用團隊

          聯系方式 xiaoming.liu@mail.zjxu.edu.cn; xiaoming.liu@ncu.edu.cn

          0573-83643937 / 15858311808

          團隊網頁:http://www.aipapr.com/xliu/

          團隊介紹

          科研團隊的負責人是浙江省錢江高級人才特聘教授劉小明博士,研究領域包括仿生催化、生物無機化學、過渡金屬配位催化等帶領團隊承擔各類研究項目17項(其中國家級課題8項)。在國際著名期刊上發表SCI研究論文110多篇、獲授權專利11項,出席國內外學術會議50余次。已培養博士研究生3名,碩士研究生近50名。本團隊還吸引了大量的本科學生進入實驗室參與教師的研究工作,自2015年以來,共有24名學生在省化學競賽中獲得一等獎。

          團隊詳細情況請見主頁http://www.aipapr.com/xliu/

          主要研究領域

          1. 仿生催化主要圍繞催化放氫的新體系和催化機理開展研究工作。

          2. 生物無機化學:基于鐵羰基化合物的一氧化碳釋放劑研究釋放方法、釋放動力學和釋放機理),并與第一附屬醫院泌尿外科的何屹主任醫生團隊開展一氧化碳釋放在腎臟手術中的應用研究;其它過渡金屬配合物及其細胞毒性和構效關系研究。

          3. 過渡金屬配位催化:銅鐵等過渡金屬催化體系(配合物均相催化、氧化物表面配位催化)催化空氣選擇性醇氧化研究。

          社會服務領域:

          本團隊在做好教學工作、應用基礎研究的同時,圍繞聚氨酯、微電子化學前驅體和高品質紡織油劑的研發和應用,與嘉興禾大科技股份有限公司、安徽博泰電子材料有限公司、桐鄉市金羊皮革化工有限公司等企業深入開展產學研合作、共同開展應用型人才培養,共計在研橫向項目3項,經費130萬。

          代表性成果(論文、專利與獲獎)

          1. Yunlian Yang, Wei Zhong, Ruonan Ma, Chunxin Lu, Zhongquan Shen, Xiaoming Liu* Shuhua Zhang* and Hongming Wang*, Engineering the surface of cuprous oxide via surface coordination for efficient catalysis on aerobic oxidation of benzylic alcohols under ambient conditions, Appl. Surf. Sci., 2021. 543, 148840.

          2. Xiujuan Jiang, Zhiyin Xiao, Wei Zhong, Xiaoming Liu*, Brief survey of diiron and monoiron carbonyl complexes and their potentials as CO-releasing molecules (CORMs), Coord. Chem. Revs., 2021, 429, 213634.

          3. Zhiyin Xiao, Natarajan Mookan, Wei Zhong, Xiaoming Liu*, Probing into the electrochemistry of four nickel(II) and cobalt(II) complexes with azadiphosphine ligands (PNP) and their catalysis on proton reduction. Electrochim. Acta, 2020, 340, 135998.

          4. Wei Zhong*, Li Wu, Weidong Jiang, Yulong Li, Natarajan Mookan, Xiaoming Liu*. Proton-coupled electron transfer in the reduction of diiron hexacarbonyl complexes and its enhancement on the electrocatalytic reduction of protons by a pendant basic group. Dalton Trans., 2019, 48, 13711–13718.

          5. Bingying Rong, Wei Zhong*, Erxing Gu, Li Long, Lijuan Song*, Xiaoming Liu*, Probing the electron transfer mechanism of the half-sandwich iron(II)-carbonyl complexes and their catalysis on proton reduction, Electrochim. Acta, 2018, 283, 2735.

          6. Jun Ou, Weihua Zheng, Zhiyin Xiao, Yuping Yan, Xiujuan Jiang, Yong Dou, Ran Jiang and Xiaoming Liu*, Core-shell materials bearing iron (II) carbonyl units and their CO-release via upconversion process, J. Mat. Chem. B., 2017, 5, 8161–8168.

          7. Wei Zhong, Zhiyin Xiao, Guifen Qian, Xiaoming Liu*, The influence of a peripheral functional group of diiron hexacarbonyl complexes on their electrochemistry and electrocatalytic reduction of proton, Electrochim. Acta, 2017, 247, 779–786.

          8. Xinglong Zhu, Wei Zhong, Xiaoming Liu*, Polymers functionalized with 1,2-benzenedithiolate-bridged model compound of [FeFe]-hydrogenase: synthesis, characterization and their catalytic activity, Int. J. Hydrogen Energy, 2016, 41, 14068–14078.

          9. Xiujuan Jiang, Limei Chen, Xiu Wang, Li Long, Zhiyin Xiao and Xiaoming Liu*, Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation, Chem. Eur. J., 2015, 21, 13065-13072.

          10. Guifen Qian, Hailong Wang, Wei Zhong and Xiaoming Liu*, Electrochemical investigation into the electron transfer mechanism of a diiron hexacarbonyl complex bearing a bridging naphthalene moiety, Electrochim. Acta, 2015, 163, 190-195.

          11. Xiujuan Jiang, Li Long, Hailong Wang, Limei Chen, Xiaoming Liu*, Diiron hexacarbonyl complexes as potential CO-RMs: their CO-releasing initiated by the substitution reaction with cysteamine and structural correlation to the bridging linkage, Dalton Trans., 2014, 43, 9968–9975.

          12. Li Long, Xiujuan Jiang, Xiu Wang, Zhiyin Xiao, Xiaoming Liu*, Water-soluble diiron hexacarbonyl complex as a CO-RM: controllable CO-releasing, releasing mechanism and biocompatibility, Dalton Trans., 2013, 42, 15663–15669.

          13. Li Long, Zhiyin Xiao, Giuseppe Zampella*, Zhenhong Wei, Luca De Gioia, Xiaoming Liu*, The reactions of pyridinyl thioesters with triirondodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations, Dalton Trans., 2012, 41, 9482–9492.

          14. Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher J. Pickett*, Xiaoming Liu*, The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(II) or low-spin Fe(0)? Chem. Commun., 2008, 3555-3557.

          15. Cédric Tard, Xiaoming Liu, Saad K. Ibrahim, Maurizio Bruschi, Luca De Gioia, Sian Davies, Xin Yang, Lai-Sheng Wang and Christopher J. Pickett*, Synthesis of the H-Cluster Framework of Iron-Only Hydrogenase, Nature, 2005, 433, 610-613.

          16. 劉小明;顧二形;姜秀娟;肖志音,水溶性鐵羰基類化合物及其制備方法和應用,專利號:ZL201810621364.X。授權日期:20210105,專利證書號:第4190070號。

          17. 沈忠權;劉小明;鐘偉;王儒杰,皮革軟化劑及其制備方法,專利號:ZL 201810565983.1。授權日期:20201211,專利證書號:第4146108號。

          18. 劉小明;姜秀娟;陳麗梅;張佳瑤;龍莉,一種促進一氧化碳釋放劑釋放一氧化碳并防止形成沉淀的方法,專利號:ZL01510180597.7授權日期:20171226專利證書號:2754331號。

          19. 鐘偉;劉小明,一種制備鄰苯二硫酚的方法,專利號:ZL201510212276.0。授權日期:20160824日,專利證書號:第2210018號。

          20. 姜秀娟;劉小明;龍莉;肖志音;曾艷,一種水溶性鐵羰基化合物及其制備方法和應用,專利號:ZL 201210175853.X。授權日期:20150114日,專利證書號:第1565669號。



           



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